I think deadliest is highly situational it would depend on say - is it 1vs1 radiant vs radiant(fused)? radiant vs army? multiple radiants vs multiple radiants? Do they have shardplates? How much stormlight do their abilities cost? Is it limited stormlight situation or are they fighting in a storm or something similar? Are they fighting in an open field or indoors?
Assuming 1vs1 full shardplate radiants in an open field I think windrunners would be strongest - their mobility would be too ridiculous, if they can manipulate winds - not only giving them ridiculous boost to their mobility beyond gravitational pulls, but it would also mess up their enemies. Pretty sure you need touch for division to work, and in that case it would not be much of an advantage over shardblade (shorter reach and would probably cost ridiculous amount of stormlight to go through shardplates). Same for elsecallers - I doubt transformation would have direct effect on radiants or shardplates. Also lashing could be used to throw rocks/blades etc exploiting blindspots.
In a limited space, assuming they are equally skilled with weapons - my bet would be on.. truthwatchers or lightweavers - illusions to blind enemy, showing multiple attacks/attackers at once, always guessing which one is real, it would be so hard to block/parry consistantly. Truthwatchers have insane regeneration if they do get hit or lightweavers manipulating enviroment with transformation, they would be insane duelists.
Against an army? Probably whoever has best aoe(maybe cheapest stormlight wise) - so stonewards or guys with division, soulcasting seems better for single objects and my impression that it's fairly "expensive".