This is a very good point. The chapter headings aren't something I'd considered before, but they do seem to strongly indicate that Shallan is in Order 6, and Jasnah Order 5.
As for Soulcasting organics, there's no reason that being in that particular Order would have any effect on her ability to Soulcast organics. Yes, number 5 on the Soulcasting chart is aligned with plants, wood, and moss, but that doesn't necessarily mean that being in Order 5 grants any special abilities with Soulcasting that Essence. Soulcasting is a Surge all on its own; it probably functions the same way regardless of which Order someone is in. The different Orders must gain access to it from a different kind of spren-bond, but the actual act of Soulcasting is probably the same for both Orders that can do it.
In chapter 72, Jasnah comments that it's harder to Soulcast something that isn't the pure form of an Essence. Presumably, you need a better comprehension of what it is you want to transform when you're working with something that isn't an Essence, and Jasnah simply doesn't know a lot about biology.
Granted, this is conjecture, but it seems logical to me.